Scientific Papers

  1. I. Fleming and J. Harley-Mason, A New Synthesis of Acetylenic Bonds and its Biosynthetic Implications, Proc. Chem. Soc., 1961, 245. (Full paper: 5)
  2. I. Fleming and J. Harley-Mason, Geometrical Isomerism in an Azine, J. Chem. Soc., 1961, 5560-5561.
  3. I. Fleming and J. Harley-Mason, A New Synthesis of Acetylenic Acids based on an Enol Elimination Reaction, Chem. Ind. (London), 1962, 560. (Full paper: 5)
  4. I. Fleming and J. Harley-Mason, A New Synthesis of Tetronic Acids, Chem. Ind. (London), 1962, 561-562. (Full paper: 6)
  5. I. Fleming and J. Harley-Mason, Enol Elimination Reactions. Part I. A New Synthesis of Acetylenic Acids, J. Chem. Soc., 1963, 4771-4778.
  6. I. Fleming and J. Harley-Mason, Enol Elimination Reactions. Part II. A New Synthesis of Tetronic Acids, J. Chem. Soc., 1963, 4778-4784.
  7. I. Fleming and J. Harley-Mason, The Reaction of Enamines with Electrophilic Olefins. A Synthesis of Cyclobutanes, J. Chem. Soc., 1964, 2165-2174.
  8. I. Fleming and J. Harley-Mason, A Synthesis of 2-Alkyltryptamines and 3,4-Dihydro-β-carboline, J. Chem. Soc. (C), 1966, 425.
  9. I. Fleming and M. H. Karger, Enamines. Part II. The Reaction of Enamines with Methyl Vinyl Ketone, J. Chem. Soc. (C), 1967, 226-235.
  10. I. Fleming, Absolute Configuration and Structure of Chlorophyll, Nature, 1967, 216, 151-152. (Full paper: 12)
  11. I. Fleming and R. B. Woodward, exo-2-Hydroxyepicamphor, J. Chem. Soc. (C), 1968, 1289-1291.
  12. I. Fleming, The Absolute Configuration and the Structure of Chlorophyll and Bacteriochlorophyll, J. Chem. Soc. (C), 1968, 2765-2770.
  13. M. J. Bishop and I. Fleming, Pericyclic Reactions. Part I. An Examination of Some Potentially Pericyclic Reactions in the Mass Spectrometer, J. Chem. Soc. (C), 1969, 1712-1718.
  14. G. W. J. Fleet and I. Fleming, Preparation of some N-Aminotriazolo-pyridines and -quinolines, their Oxidation with Lead Tetra-acetate and the Trapping of the Resulting Pyridynes and Quinolynes with Tetraphenylcyclopentadienone (Tetracyclone), J. Chem. Soc. (C), 1969, 1758-1763.
  15. I. Fleming, Reaction of Some Thiamine Analogues with Bis-(3-methylbut-2-enyl)disulphide, Chem. Ind. (London), 1969, 1661.
  16. I. Fleming and J. B. Mason, A Product from the Reaction of Pyridine with Acetic Anhydride, J. Chem. Soc. (C), 1969, 2509-2510.
  17. I. Fleming and E. Wildsmith, Pericyclic Reactions. The Synthesis and Reactions of Deuterium Labelled Cyclohexa-1,4-diene and Cyclohexa-1,3-diene, Chem. Commun., 1970, 223-224.
  18. I. Fleming and D. Philippides, Equilibrium between 4-Acetoxypyridine and N-Acetyl-4-pyridone; a Correction of the Literature, J. Chem. Soc. (C), 1970, 2426-2428.
  19. M. J. Bishop and I. Fleming, Synthesis of Dimethyl Bicyclo[3,2,2]nona-2,6,8-triene-6,7-dicarboxylate, J. Chem. Soc. (C), 1970, 2524-2528.
  20. I. Fleming and C. R. Owen, A Sulphur Equivalent of the Perkow Reaction, Chem. Commun., 1970, 1402. (Full paper: 21)
  21. I. Fleming and C. R. Owen, Enol Elimination Reactions. Part IV. Some Improvements to the Synthesis of Conjugated Acetylenic Acids, J. Chem. Soc. (C), 1971, 2013-2017.
  22. I. Fleming and C. R. Owen, Enol Elimination Reactions. Part V. A Study of the Mechanism of the Decarboxylative Elimination Reaction of Some Enol Sulphonates, J. Chem. Soc. (B), 1971, 1293-1299.
  23. I. Fleming and E. J. Thomas, The Rearrangement of Cyclopropyl Chlorides to Allyl Chlorides: Stereospecificity in the Recapture of the Chloride Ion, Tetrahedron Lett., 1971, 2485-2488. (Full paper: 28)
  24. I. Fleming, S. W. Hanson and J. K. M. Sanders, The Effect of Eu(DPM)3 on the NMR Spectra of Some Bifunctional Compounds, Tetrahedron Lett., 1971, 3733-3736.
  25. I. Fleming, A. V. Kemp-Jones and E. J. Thomas, Cyclobutanol-to-Fragmentation Ratios for the Singlet and Triplet States in the Photochemistry of cis-2-Propyl-4-t-butylcyclohexanone, Chem. Commun., 1971, 1158-1159. (Full paper: 38)
  26. G. W. J. Fleet, I. Fleming and D. Philippides, The Addition of Acetic Acid to Pyridynes and Quinolynes, J. Chem. Soc. (C), 1971, 3948-3950.
  27. I. Fleming, N. Hatanaka, H. Ohta, O. Simamura and M. Yoshida, A Revised Structure for the Product from the Decomposition of an o-Quinone Oxime Benzenesulphonate, Chem. Commun., 1972, 242-243.
  28. I. Fleming and E. J. Thomas, The Rearrangement of Cyclopropyl Chlorides to Allyl Chlorides, Tetrahedron, 1972, 28, 4989-5001.
  29. I. Fleming and E. J. Thomas, The Reaction of a Monochlorocarbenoid with some Methoxycycloalkenes - an Observation on the Mechanism of the Insertion Reaction of Carbenes into Double Bonds, Tetrahedron, 1972, 28, 5003-5010.
  30. I. Fleming, Synthesis of the 8-Cycloheptatrienylheptafulvenyl Cation, J. Chem. Soc. Perkin Trans. 1, 1973, 1019-1021.
  31. I. Fleming and R. B. Woodward, A Synthesis of (-)-(R)-trans-β-(1,2,3-Trimethylcyclopent-2-enyl)acrylic Acid, J. Chem. Soc. Perkin Trans. 1, 1973, 1653-1657.
  32. E. H. Billett and I. Fleming, The Intramolecular Reaction between a Diazoalkane Group and an Ester Group: the First Example, J. Chem. Soc. Perkin Trans. 1, 1973, 1658-1661.
  33. E. H. Billett, I. Fleming and S. W. Hanson, The Intramolecular Reaction between a Diazoalkane Group and an Ester Group: a Search for Other Examples, J. Chem. Soc. Perkin Trans. 1, 1973, 1661-1668.
  34. I. Fleming and S. W. Hanson, The Intramolecular Reaction between a Diazoalkane Group and an Ester Group: the Second Example, J. Chem. Soc. Perkin Trans. 1, 1973, 1669-1675.
  35. I. Fleming and W. E. Long, A Protected 5-Hydroxypentanal Synthon, Synth. Commun., 1975, 5, 177-180.
  36. I. Fleming and T. Mah, A Simple Synthesis of Anthracenes, J. Chem. Soc. Perkin Trans. 1, 1975, 964-965.
  37. I. Fleming and A. Pearce, Aliphatic Friedel-Crafts Acylation of Vinylsilanes, J. Chem. Soc., Chem. Commun., 1975, 633. (Full paper: 68)
  38. I. Fleming, A. V. Kemp-Jones, W. E. Long and E. J. Thomas, Cyclobutanol:Fragmentation Ratios for the Singlet and Triplet Excited States in the Type II Photochemistry of Some α-Alkylated Cyclohexanones, J. Chem. Soc. Perkin Trans. 2, 1976, 7-14.
  39. I. Fleming and W. E. Long, Photosensitisation in the Photolysis of Saturated Ketones, J. Chem. Soc. Perkin Trans. 2, 1976, 14-15.
  40. I. Fleming, A. Pearce and R. L. Snowden, Controlling the Outcome of a Carbonium Ion Reaction: the Use of a Trimethylsilyl Group to Dictate the Formation of a Specific Olefin, J. Chem. Soc., Chem. Commun., 1976, 182. (Full papers: 49 and 69)
  41. I. Fleming, F. L. Gianni and T. Mah, The Regioselectivity of the Diels-Alder Reaction between a Diene with an Electron-Donating Substituent and a Dienophile with an Electron-Donating Substituent: A Test Case for Frontier Orbital Theory, Tetrahedron Lett., 1976, 881-884.
  42. I. Fleming and T. Mah, Preparation of Benzyne from Phenyl Benzenesulphonate, J. Chem. Soc. Perkin Trans. 1, 1976, 1577-1579.
  43. M. J. Carter and I. Fleming, Allyl Silanes in Organic Synthesis: Some Reactions of 3-Trimethylsilylcyclohex-4-ene-1,2-dicarboxylic Acid and its Derivatives, J. Chem. Soc., Chem. Commun., 1976, 679-680. (Full paper: 79)
  44. I. Fleming and A. Percival, Regioselectivity in the Diels-Alder Reaction of 1-Trimethylsilylbutadiene, J. Chem. Soc., Chem. Commun., 1976, 681. (Full paper: 79)
  45. P. Brownbridge, I. Fleming, A. Pearce and S. Warren, Formation of Allylsulphides by Phenylthio Migration: Effects of Alkyl Substitution and Control by Silicon, J. Chem. Soc., Chem. Commun., 1976, 751-752. (Full paper: 70)
  46. D. J. Ager and I. Fleming, The Trityldimethylsilyl Group for the Protection and Characterisation of Alcohols, J. Chem. Res. (S), 1977, 6-7; J. Chem. Res. (M), 1977, 0136-0152.
  47. B.-W. Au-Yeung and I. Fleming, Allylsilanes in Organic Synthesis: a Synthesis of Prostaglandins, J. Chem. Soc., Chem. Commun., 1977, 79-80. (Full paper: 77)
  48. B.-W. Au-Yeung and I. Fleming, Allylsilanes in Organic Synthesis: a New Synthesis of Loganin, J. Chem. Soc., Chem. Commun., 1977, 81. (Full paper: 77)
  49. A. H. Davidson, I. Fleming, J. I. Grayson, A. Pearce, R. L. Snowden and S. Warren, Regioselectivity and Control in Alkene Formation from a Carbonium Ion after Diphenylphosphinoyl Migration, J. Chem. Soc. Perkin Trans. 1, 1977, 550-565.
  50. I. Fleming and J. Goldhill, β-Silylketones as Masked αβ-Unsaturated Ketones, J. Chem. Soc., Chem. Commun., 1978, 176. (Full paper: 67)
  51. D. J. Ager and I. Fleming, A Silicon-based Protecting Group for the αβ-Unsaturation of αβ-Unsaturated Ketones, J. Chem. Soc., Chem. Commun., 1978, 177. (Full paper: 81)
  52. I. Fleming and A. Percival, Regioselectivity in the Diels-Alder Reactions of 3- and 4-Substituted 1-Trimethylsilylbutadienes, J. Chem. Soc., Chem. Commun., 1978, 178-179. (Full paper: 79)
  53. I. Fleming and J. P. Michael, Carbonium Ion Rearrangements in the Norbornyl Series Controlled by a Silyl Group, J. Chem. Soc., Chem. Commun., 1978, 245. (Full paper: 75)
  54. I. Fleming, J. P. Michael, L. E. Overman and G. F. Taylor, How Important is Secondary Overlap in Determining the Regioselectivity of Diels-Alder Reactions? Tetrahedron Lett., 1978, 1313-1314.
  55. I. Paterson and I. Fleming, α-Methylenation of Lactones and Esters: Zinc Bromide-Catalysed Phenythiomethylation of O-Silylated Enolates, Tetrahedron Lett., 1979, 993-994.
  56. I. Paterson and I. Fleming, Regiospecific α-Methylenation and α-Methylation of Ketones: Titanium Tetrachloride Promoted Phenylthiomethylation of Silyl Enol Ethers, Tetrahedron Lett., 1979, 995-998.
  57. I. Fleming and M. Woolias, A Benzyne Route to Indoles from o- or m-Bromoaryl Ketones, J. Chem. Soc. Perkin Trans. 1, 1979, 827-828.
  58. I. Fleming and M. Woolias, A New Synthesis of Indoles Particularly Suitable for the Synthesis of Tryptamines and Tryptamine Itself, J. Chem. Soc. Perkin Trans. 1, 1979, 829-837.
  59. I. Paterson and I. Fleming, α-Alkylation and α-Alkylidenation of Carbonyl Compounds: Lewis Acid-Promoted Phenylthioalkylation of O-Silylated Enolates, Tetrahedron Lett., 1979, 2179-2182.
  60. I. Fleming, P. G. Jones, O. Kennard and J. P. Michael, Bromine-initiated Silicon-assisted Rearrangement in the Norbornene Series: Crystal and Molecular Structure of 3-endo,5-endo-Dibromotricyclo[2.2.1.02,6]heptane-7-carboxylic Acid, J. Chem. Soc. Perkin Trans. 2, 1979, 808- 809.
  61. I. Fleming and I. Paterson, Allylsilanes in Organic Synthesis: A Method for the Introduction of Two Carbon Substituents in Place of Carbonyl Oxygen, Synthesis, 1979, 446-448.
  62. I. Fleming, J. Goldhill and I. Paterson, γ-Sulphenylation of αβ-Unsaturated Aldehydes, Ketones and Esters: The Use of O-Silylated Dienolates, Tetrahedron Lett., 1979, 3205-3208.
  63. I. Fleming, J. Goldhill and I. Paterson, γ-Alkylation of Unsaturated Ketones and Esters: Zinc Bromide-Catalysed Alkylation of O-Silylated Dienolates, Tetrahedron Lett., 1979, 3209-3212.
  64. I. Fleming and I. Paterson, A Simple Synthesis of Carvone Using Silyl Enol Ethers, Synthesis, 1979, 736-738.
  65. W. B. T. Cruse, I. Fleming, P. T. Gallagher and O. Kennard, The Stereochemistry of the Diels-Alder Reactions of Fumaric Acid Derivatives, J. Chem. Res. (S), 1979, 372-373, J. Chem. Res. (M), 1979, 4418-4437.
  66. I. Fleming and F. Roessler, Reaction of a Silyl-Copper Reagent with Acetylenes: a New Synthesis of Vinylsilanes, J. Chem. Soc., Chem. Commun., 1980, 276-277. (Full paper: 82)
  67. I. Fleming and J. Goldhill, α-Silylcarbonyl Compounds as Masked Enones, J. Chem. Soc. Perkin Trans. 1, 1980, 1493-1498.
  68. I. Fleming and A. Pearce, Friedel-Crafts Reactions of Some Vinylsilanes, J. Chem. Soc. Perkin Trans. 1, 1980, 2485-2489.
  69. I. Fleming and A. Pearce, Controlling the Outcome of a Carbocation-Initiated Cyclisation, J. Chem. Soc. Perkin Trans. 1, 1981, 251-255.
  70. I. Fleming, I. Paterson and A. Pearce, The Formation of Allylsulphides by Phenylthio-migration: Control by Silicon, J. Chem. Soc. Perkin Trans. 1, 1981, 256-262.
  71. I. Fleming and T. V. Lee, The γ-Alkylation of Enones Using Silyl Enol Ethers: The Effect of Changing the Electrophile and of Changing the Silyl Group, Tetrahedron Lett., 1981, 22, 705-708.
  72. I. Fleming and R. V. Williams, The Reaction between Bis(trimethylsilyl)cyclopentadiene and Dichloroketen and the Diels-Alder Reactions between N-Phenylmaleimide and Two Silylated Methylcyclopentadienes, J. Chem. Soc. Perkin Trans. 1, 1981, 684-688.
  73. I. Fleming and C. D. Floyd, The Reactions of Tris(trimethylsilyl)methyl-Lithium with some Carbon Electrophiles, J. Chem. Soc. Perkin Trans. 1, 1981, 969-976.
  74. I. Fleming and J. A. Langley, The Mechanism of the Protodesilylation of Allylsilanes and Vinylsilanes, J. Chem. Soc. Perkin Trans. 1, 1981, 1421-1423.
  75. I. Fleming and J. P. Michael, Synthetic Studies with 7-Functionalised Norbornenes and their Synthesis by a Silicon-Controlled Carbocation Rearrangement, J. Chem. Soc. Perkin Trans. 1, 1981, 1549-1556.
  76. I. Fleming and S. K. Patel, Carbonium Ion Rearrangements Controlled by the Presence of a Silyl Group, Tetrahedron Lett., 1981, 2321-2324. (Full paper: 133)
  77. I. Fleming and B.-W. Au-Yeung, The Chemistry of an Allylsilane: The Synthesis of a Prostaglandin Intermediate and of Loganin, Tetrahedron Supplement No. 9, 1981, 37 Supplement No. 1, 13-24.
  78. I. Fleming and D. Marchi, A New Synthesis of Allylsilanes, Synthesis, 1981, 560-561.
  79. M. J. Carter, I. Fleming and A. Percival, The Diels-Alder Route to Allylsilanes from 1-Trimethylsilylbutadienes, J. Chem. Soc. Perkin Trans. 1, 1981, 2415-2434.
  80. I. Fleming, D. Marchi and S. K. Patel, The Mechanism of the Protodesilylation of Allylsilanes which are Disubstituted on C-3, J. Chem. Soc. Perkin Trans. 1, 1981, 2518-2519.
  81. D. J. Ager, I. Fleming and S. K. Patel, The Conjugate Addition of a Silyl Group to Enones and its Removal with Copper(II) Bromide: A Protecting Group for the αβ-Unsaturation of αβ-Unsaturated Ketones, J. Chem. Soc. Perkin Trans. 1, 1981, 2520-2526.
  82. I. Fleming, T. W. Newton and F. Roessler, The Silyl-Cupration of Acetylenes: A Synthesis of Vinylsilanes, J. Chem. Soc. Perkin Trans. 1, 1981, 2527-2532.
  83. I. Fleming and D. A. Perry, Cyclo-elimination of Silyl and Sulphoxide Groups in Competition with the Conventional Cyclo-elimination of Sulphoxides, Tetrahedron Lett., 1981, 22, 5095-5096. (Full paper: 86)
  84. I. Fleming and D. A. Perry, The Synthesis of αβ-Unsaturated Ketones from β-Silylenones and β-Silylynones, Tetrahedron, 1981, 37, 4027-4034.
  85. I. Fleming, M. A. Loreto, J. P. Michael and I. H. M. Wallace, Two New Stereochemically Complementary Oxindole Syntheses, Tetrahedron Lett., 1982, 23, 2053-2056. (Full paper: 111)
  86. I. Fleming, J. Goldhill and D. A. Perry, Cycloelimination of β-Silylethyl Sulphoxides: Alkene, Alkyne and Vinylsilane-forming Reactions, J. Chem. Soc. Perkin Trans. 1, 1982, 1563-1569.
  87. I. Fleming and J. Iqbal, Phenylthioalkylation-Desulphurisation for the C-Alkylation of Phenols, Synthesis, 1982, 937-939.
  88. I. Fleming and J. Iqbal, The Methoxycarbonylation and Methoxycarbonyl-alkylidenation of Silyl Enol Ethers, Tetrahedron Lett., 1983, 24, 327-328.
  89. I. Fleming, J. Iqbal and E.-P. Krebs, The Total Synthesis of (±)-Trichostatin A. Some Observations on the Acylation of Silyl Enol Ethers, Silyl Dienol Ethers and a Silyl Trienol Ether, Tetrahedron, 1983, 39, 841-846.
  90. I. Fleming and J. Iqbal, α:γ Ratios in Phenylthiomethylation of Silyl Dienol Ethers, Tetrahedron Lett., 1983, 24, 2913-2916.
  91. I. Fleming and N. K. Terrett, Stereospecificity in the Synthesis of Allylsilanes from Tertiary Allylic Acetates, Tetrahedron Lett., 1983, 24, 4151-4152. (Full paper: 97)
  92. I. Fleming and N. K. Terrett, The Stereochemistry of Some SE2' Reactions of Allyl- and Allenylsilanes, Tetrahedron Lett., 1983, 24, 4153-4156. (Full paper: 97)
  93. I. Fleming and C. J. Urch, Stereospecific Cyclopropane Synthesis from γ-Stannyl Alcohols, Tetrahedron Lett., 1983, 24, 4591-4594. (Full paper: 107)
  94. I. Fleming and T. W. Newton, Stereospecific Rearrangement of 2,2-Disubstituted Vinylsilane Epoxides to the Silyl Enol Ethers of 2,2-Disubstituted Aldehydes, J. Chem. Soc. Perkin Trans. 1, 1984, 119-123.
  95. W. Bernhard, I. Fleming and D. Waterson, Diastereoselectivity in the Alkylation of Enolates having an Adjacent Silyl Group, J. Chem. Soc., Chem. Commun., 1984, 28-29. (Full papers: 101 and 156)
  96. I. Fleming, R. Henning and H. Plaut, The Phenyldimethylsilyl Group as a Masked Form of the Hydroxy Group, J. Chem. Soc., Chem. Commun., 1984, 29-31. (Full paper: 181)
  97. I. Fleming and N. K. Terrett, Stereospecific Syntheses and Reactions of Allyl- and Allenyl-Silanes, J. Organomet. Chem., 1984, 264, 99-118.
  98. I. Fleming and T. W. Newton, Observations on Various Silyl-cuprate Reagents, J. Chem. Soc. Perkin Trans. 1, 1984, 1805-1808.
  99. I. Fleming and D. Waterson, A Synthesis of Allylsilanes in which the Silyl Group is at the More-substituted End of the Allyl Group, J. Chem. Soc. Perkin Trans. 1, 1984, 1809-1813.
  100. H.-F. Chow and I. Fleming, Controlling the Outcome of a Carbocation-initiated Cyclisation, J. Chem. Soc. Perkin Trans. 1, 1984, 1815-1819.
  101. W. Bernhard and I. Fleming, The Relative Stereochemistry of Some α-Methyl-β-silylcarbonyl Compounds Produced by the Diastereoselective Alkylation of β-Silylenolates, J. Organomet. Chem., 1984, 271, 281-288.
  102. I. Fleming and N. K. Terrett, Stereospecific Allylsilane Reactions: A Total Synthesis of Dihydronepetalactone, Tetrahedron Lett., 1984, 25, 5103-5104. (Full paper: 199)
  103. H.-F. Chow and I. Fleming, A Synthesis of the Prelog-Djerassi Lactone Using Open-Chain Stereocontrol Based on Allylsilane Chemistry, Tetrahedron Lett., 1985, 26, 397-400. (Full paper: 200)
  104. I. Fleming and J. J. Lewis, A Paradigm for Diastereoselectivity in Electrophilic Attack on Trigonal Carbon Adjacent to a Chiral Centre: the Methylation and Protonation of Some Open-chain Enolates, J. Chem. Soc., Chem. Commun., 1985, 149-151. (Full paper: 154)
  105. I. Fleming, J. H. M. Hill, D. Parker and D. Waterson, Diastereoselectivity in the Alkylation and Protonation of Some β-Silyl Enolates, J. Chem. Soc., Chem. Commun., 1985, 318-321. (Full paper: 156)
  106. I. Fleming and A. P. Thomas, Regiocontrolled Allylsilane Synthesis from Secondary Allylic Alcohol Derivatives, J. Chem. Soc., Chem. Commun., 1985, 411-413. (Full paper: 161)
  107. I. Fleming and C. J. Urch, Stereospecific Cyclopropane Synthesis from γ-Stannyl Alcohols, J. Organomet. Chem., 1985, 285, 173-191.
  108. I. Fleming and M. Rowley, The Stereochemistry of Attack by a Carbon Electrophile on a Tin-Carbon Bond, Tetrahedron Lett., 1985, 26, 3857-3858. (Full paper: 114)
  109. I. Fleming and M. Taddei, A Simple Synthesis of 3-Tributylstannylfuran and 3-Lithiofuran, Synthesis, 1985, 898.
  110. I. Fleming and M. Taddei, A Simple Synthesis of 2-Silyl- and 2-Stannyl-1,3-butadienes, Synthesis, 1985, 899-900.
  111. I. Fleming, M. A. Loreto, I. H. M. Wallace and J. P. Michael, Two New Oxindole Syntheses, J. Chem. Soc. Perkin Trans. 1, 1986, 349-359.
  112. I. Fleming and J. D. Kilburn, Diastereoselective Aldol Reactions of β-Silylenolates, J. Chem. Soc., Chem. Commun., 1986, 305-306. (Full paper: 157)
  113. I. Fleming, H. Kühne and K. Takaki, Nucleophilic Attack on a Carbonyl Group Conjugated to a Chiral Centre: A Search for a Vinylogous Cram's Rule, J. Chem. Soc. Perkin Trans. 1, 1986, 725-728.
  114. I. Fleming and M. Rowley, The Stereochemistry of the Intramolecular Electrophilic Attack of an Aldehyde on a Carbon-Tin Bond, Tetrahedron, 1986, 42, 3181-3198.
  115. I. Fleming and F. J. Pulido, The Synthesis of Allylsilanes and Vinylsilanes by Silyl-cupration of Allenes, J. Chem. Soc., Chem. Commun., 1986, 1010-1011. (Full paper: 135)
  116. I. Fleming and J. D. Kilburn, Diastereoselective Aldol Reactions of β-Silylenolates: a Formal Synthesis of Thienamycin, J. Chem. Soc., Chem. Commun., 1986, 1198-1199. (Full paper: 201)
  117. I. Fleming and A. K. Sarkar, Diastereoselective Aldol Reactions of β-Silylenolates: a New Regiocontrolled Synthesis of Allylsilanes, J. Chem. Soc., Chem. Commun., 1986, 1199-1201. (Full paper: 162)
  118. W. Engel, I. Fleming and R. H. Smithers, The Effect of a β-Silyl Group on the Regiochemistry of Enolisation of Ketones, J. Chem. Soc. Perkin Trans. 1, 1986, 1637-1641.
  119. I. Fleming and A. P. Thomas, A Stereospecific Synthesis of Optically Active Allylsilanes, J. Chem. Soc., Chem. Commun., 1986, 1456-1457. (Full paper: 161)
  120. I. Fleming and M. Rowley, A Regiocontrolled Synthesis of Allylstannanes, Tetrahedron Lett., 1986, 27, 5417-5420. (Full paper: 125)
  121. I. Fleming, A. K. Sarkar and A. P. Thomas, The Stereochemistry of Osmylation, Epoxidation and Methylenation of Allylsilanes, J. Chem. Soc., Chem. Commun., 1987, 157-159. (Full paper: 158)
  122. I. Fleming and N. D. Kindon, Diastereoselectivity in the Preparation of β-Silylesters from αβ-Unsaturated Esters and Amides Attached to Chiral Auxiliaries, J. Chem. Soc., Chem. Commun., 1987, 1177-1179. (Full paper: 180)
  123. I. Fleming and P. E. J. Sanderson, A One-Pot Conversion of the Phenyldimethylsilyl Group into a Hydroxyl Group, Tetrahedron Lett., 1987, 28, 4229-4232. (Full paper: 181)
  124. I. Fleming, N. L. Reddy, K. Takaki and A. C. Ware, Stereochemistry of Conjugate Addition to 4- and 5-Substituted δ-Lactones, J. Chem. Soc., Chem. Commun., 1987, 1472-1474. (Full paper: 231)
  125. I. Fleming and M. Rowley, A Regiocontrolled Synthesis of Allylstannanes, J. Chem. Soc. Perkin Trans. 1, 1987, 2259-2264.
  126. I. Fleming, K. Takaki and A. P. Thomas, Synthesis of Allenylsilanes from Propargyl Carbamates, J. Chem. Soc. Perkin Trans. 1, 1987, 2269-2273.
  127. I. Fleming, N. D. Kindon and A. K. Sarkar, The Stereochemistry of an SE2" Reaction of a Chiral Dienylmethylsilane, Tetrahedron Lett., 1987, 28, 5921-5924. (Full paper: 184)
  128. P. Cuadrado, A. M. González, F. J. Pulido and I. Fleming, Silyl-Cupration of Allene. A New Route to Silylated Synthons, Tetrahedron Lett., 1988, 29, 1825-1826. (Full paper: 135)
  129. I. Fleming and N. J. Lawrence, Regiochemistry in the Hydroboration of Allylsilanes, Tetrahedron Lett., 1988, 29, 2073-2076. (Full paper: 159)
  130. I. Fleming and N. J. Lawrence, Stereochemistry in the Hydroboration of Allylsilanes, Tetrahedron Lett., 1988, 29, 2077-2080. (Full paper: 159)
  131. J. E. McMurry, J. H. Musser, I. Fleming, J. Fortunak and C. Nübling, Methyl (E)-3-Nitroacrylate, Org. Synth., Coll. Vol. VI, 1988, 799-803.
  132. C. Clarke, I. Fleming, J. M. D. Fortunak, P. T. Gallagher, M. C. Honan, A. Mann, C. O. Nübling, P. R. Raithby and J. J. Wolff, An Approach to the Synthesis of Gelsemine: The Intramolecular Reaction of an Allylsilane with an Acyliminium Ion for the Synthesis of One of the Quaternary Centres, Tetrahedron, 1988, 43, 3931-3944.
  133. I. Fleming, S. K. Patel and C. J. Urch, Carbonium Ion Rearrangements Controlled by the Presence of a Silyl Group, J. Chem. Soc. Perkin Trans. 1, 1989, 115-124.
  134. I. Fleming and D. Higgins, Protodesilylation of Allylsilanes for the Control of Double Bond Geometry Exocyclic to a Ring, J. Chem. Soc. Perkin Trans. 1, 1989, 206-207. (Full paper: 160)
  135. I. Fleming, M. Rowley, P. Cuadrado, A. M. González-Nogal and F. J. Pulido, The Silyl-Cupration and Stannyl-Cupration of Allenes, Tetrahedron, 1989, 45, 413-424.
  136. I. Fleming, S. K. Armstrong and R. J. Pollitt, Synthesis of 3-Ethyl-3-hydroxy-δ-valerolactone, a Homologue of Mevalonolactone and a Metabolite in Propionic Acidaemia, J. Chem. Res., 1989, 19.
  137. I. Fleming and D. Higgins, The Stereospecific Synthesis of a Carbacyclin Analogue Using the Protodesilylation of an Allylsilane, Tetrahedron Lett., 1989, 30, 5777-5780. (Full paper: 202)
  138. I. Fleming, A. K. Sarkar, M. J. Doyle and P. R. Raithby, Diastereofacial Selectivity in Diels-Alder Reactions of a Diene having a Stereogenic Centre carrying a Silyl Group Adjacent to the Diene System, J. Chem. Soc. Perkin Trans. 1, 1989, 2023-2030.
  139. I. Fleming and N. J. Lawrence, A Synthesis of (-)-Tetrahydrolipstatin in which the Relative Stereochemistry is Controlled by a Phenyldimethylsilyl Group, Tetrahedron Lett., 1990, 31, 3645-3648. (Full paper: 203)
  140. A. Barbero, P. Cuadrado, I. Fleming, A. M. González-Nogal and F. J. Pulido, The Synthesis of Allylstannanes and Vinylstannanes by the Stannyl-cupration of Allenes, J. Chem. Soc., Chem. Commun., 1990, 1030-1031. (Full paper: 147)
  141. A. Barbero, P. Cuadrado, I. Fleming, A. M. González and F. J. Pulido, Selective Transfer of a Stannyl Group from a Mixed Silyl(stannyl)cuprate, J. Chem. Res. (S), 1990, 291.
  142. I. Fleming, I. T. Morgan and A. K. Sarkar, The Stereochemistry of the Vinylogous Peterson Elimination, J. Chem. Soc., Chem. Commun., 1990, 1575-1577. (Full paper: 209)
  143. I. Fleming, R. C. Moses, M. Tercel and J. Ziv, A New Oxindole Synthesis, J. Chem. Soc. Perkin Trans. 1, 1991, 617-626.
  144. I. Fleming, Y. Landais and P. R. Raithby, The Stereochemistry of the Silyl-Cupration of Allenes, J. Chem. Soc. Perkin Trans. 1, 1991, 715-719.
  145. A. Barbero, P. Cuadrado, A. M. González, F. J. Pulido and I. Fleming, The Reaction of tert-Butyldiphenylsilylcuprates with Allenes, J. Chem. Soc. Perkin Trans. 1, 1991, 2811-2816.
  146. N. Abd. Rahman and I. Fleming, Desilylation Reaction of Allyl(dimethyl)-5-methyl-2-furylsilane, Malaysian J. Sci. , 1991, 13, 67-73.
  147. A. Barbero, P. Cuadrado, I. Fleming, A. M. González and F. J. Pulido, Synthesis of Allylstannanes and Vinylstannanes by the Stannyl-cupration of Allenes, J. Chem. Soc. Perkin Trans. 1, 1992, 327-331.
  148. A. Barbero, P. Cuadrado, I. Fleming, A. M. González and F. J. Pulido, The Stannyl-Cupration of Acetylenes and the Reaction of the Intermediate Cuprates with Electrophiles as a Synthesis of Substituted Vinylstannanes, J. Chem. Soc., Chem. Commun., 1992, 351-353. (Full paper: 171)
  149. I. Fleming, P. E. J. Sanderson and N. K. Terrett, The Regiochemistry of the Protodesilylation of Some Cyclopropylmethylsilanes Derived from Allylsilanes, Synthesis, 1992, 69-74.
  150. M. J. C. Buckle, I. Fleming and S. Gil, Accurate Determination of the Extent to which an SE2' Reaction of an Allylsilane is anti, Tetrahedron Lett., 1992, 33, 4479-4482. (Full paper: 229)
  151. N. Abd.Rahman, I. Fleming and A. B. Zwicky, Failure in Several Attempts to Prepare Arylsilyl-lithium Reagents by the Gilman Cleavage of Disilanes with Lithium, J. Chem. Res. (S), 1992, 292; J. Chem. Res. (M), 1992, 2401-2408.
  152. I. Fleming, T. W. Newton, V. Sabin and F. Zammattio, The Synthesis of 3-Trimethylsilyl-4-dimethyl(phenyl)silylbut-3-en-2-one, a β-Functionalised Michael Acceptor, Tetrahedron, 1992, 48, 7793-7802.
  153. A. Barbero, P. Cuadrado, A. M. González, F. J. Pulido, R. Rubio and I. Fleming, Ring-Formation from Allyl- and Vinylstannanes Initiated by Treatment with Butyl-Lithium, Tetrahedron Lett., 1992, 33, 5841-5842.
  154. I. Fleming and J. J. Lewis, The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-Chain Enolates Having a Stereogenic Centre at the β Position, J. Chem. Soc. Perkin Trans. 1, 1992, 3257- 3265.
  155. I. Fleming and J. J. Lewis, The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre: Diastereoselective Protonation, Epoxidation and Acylation of Allylsilanes, J. Chem. Soc. Perkin Trans. 1, 1992, 3267-3275.
  156. R. A. N. C. Crump, I. Fleming, J. H. M. Hill, D. Parker, N. L. Reddy and D. Waterson, The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-Chain Enolates Having a Stereogenic Centre Carrying a Silyl Group at the β Position, J. Chem. Soc. Perkin Trans. 1, 1992, 3277-3294.
  157. I. Fleming and J. D. Kilburn, The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre: Diastereoselective Aldol Reactions of Open-Chain Enolates Having a Stereogenic Centre Carrying a Silyl Group at the β Position, J. Chem. Soc. Perkin Trans. 1, 1992, 3295-3302.
  158. I. Fleming, N. J. Lawrence, A. K. Sarkar and A. P. Thomas, The Stereochemistry of the Reaction of Allylsilanes with Osmium Tetroxide and of the Epoxidation and Methylenation of Allylsilanes, J. Chem. Soc. Perkin Trans. 1, 1992, 3303-3308.
  159. I. Fleming and N. J. Lawrence, The Regiochemistry and Stereochemistry of the Hydroboration of Allylsilanes, J. Chem. Soc. Perkin Trans. 1, 1992, 3309-3326.
  160. I. Fleming and D. Higgins, Protodesilylation of Allylsilanes for the Control of Double Bond Geometry Exocyclic to a Ring, J. Chem. Soc. Perkin Trans. 1, 1992, 3327-3329.
  161. I. Fleming, D. Higgins, N. J. Lawrence and A. P. Thomas, A Regioselective and Stereospecific Synthesis of Allylsilanes from Secondary Allylic Alcohol Derivatives, J. Chem. Soc. Perkin Trans. 1, 1992, 3331-3349.
  162. I. Fleming, S. Gil, A. K. Sarkar and T. Schmidlin, A Regiocontrolled and Stereocontrolled Synthesis of Allylsilanes from β-Silylenolates, J. Chem. Soc. Perkin Trans. 1, 1992, 3351-3361.
  163. I. Fleming, The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent to a Stereogenic Centre, J. Chem. Soc. Perkin Trans. 1, 1992, 3363-3369.
  164. I. Fleming and S. K. Ghosh, Stereoselective Samarium(II)-induced Coupling of β-Silylacrylic Esters: A Synthesis of (±)-2-Deoxyribonolactone, J. Chem. Soc., Chem. Commun., 1992, 1775-1777. (Full paper: 206)
  165. I. Fleming and S. K. Ghosh, Stereospecific 1,2-Silyl Shift in a Cationic Rearrangement with Retention of Configuration at the Migration Origin, J. Chem. Soc., Chem. Commun., 1992, 1777-1779. (Full paper: 206)
  166. I. Fleming and E. Martínez de Marigorta, Silyl-Cupration of an Acetylene Followed by Ring-Formation, Tetrahedron Lett., 1993, 34, 1201-1204. (Full paper: 210)
  167. M. J. C. Buckle and I. Fleming, Accurate Determination of the Extent to which the SE2' Reactions of an Allenylsilane are Stereospecifically anti, Tetrahedron Lett., 1993, 34, 2383-2386. (Full paper: 229)
  168. S. C. Archibald and I. Fleming, Some Byproducts in the SE2' Reactions of an Allenylsilane with Aldehydes, Tetrahedron Lett., 1993, 34, 2387-2390.
  169. S. C. Archibald and I. Fleming, Two Unexpected but Understandable Reactions with Lithium Diisopropyl Amide (LDA), J. Chem. Soc. Perkin Trans. 1, 1993, 751-754.
  170. N. Abd. Rahman and I. Fleming, Compatibility Studies of Dimethyl(phenyl)silyl Group as a Masked Hydroxyl Group in Compounds Containing Cyclopropane Rings and in Compounds Containing the Enone Functionality, Synth. Commun., 1993, 23, 1583-1594.
  171. A. Barbero, P. Cuadrado, I. Fleming, A. M. González, F. J. Pulido and R. Rubio, Stannyl-Cupration of Acetylenes and the Reaction of the Intermediate Cuprates with Electrophiles as a Synthesis of Substituted Vinylstannanes, J. Chem. Soc. Perkin Trans. 1, 1993, 1657-1662.
  172. I. Fleming and S. B. D. Winter, The 2-Methylbut-2-enyl(diphenyl)silyl Group: A Silyl Group Easily Converted to Hydroxyl in the Presence of a 1,2-Disubstituted C=C Double Bond, Tetrahedron Lett., 1993, 34, 7287-7290. (Full paper: 204)
  173. I. Fleming and S. K. Ghosh, A Simple Method for enriching the Enantiomeric Purity of a Functional Molecule already Rich in One Enantiomer, J. Chem. Soc., Chem. Commun., 1994, 99-100. (Full paper: 208)
  174. I. Fleming and U. Ghosh, Synthesis of Acylsilanes from Amides and Esters, and the Selective Oxidation of α-Silyl Alcohols to Aldehydes, J. Chem. Soc. Perkin Trans. 1, 1994, 257-262.
  175. R. A. N. C. Crump, I. Fleming and C. J. Urch, Conjugate Addition of the Phenyldimethylsilyl Group to α,β-Unsaturated Carbonyl Compounds Using a Silylzincate in Place of the Silylcuprate, J. Chem. Soc. Perkin Trans. 1, 1994, 701-706.
  176. I. Fleming, P. E. J. Sanderson and F. Zammattio, Chromium Tricarbonyl Complexes of Dimethyl(phenyl)allylsilanes and their Treatment with Fluoride Ion, J. Chem. Res. (S), 1994, 159; J. Chem. Res. (M), 1994, 1020-1025.
  177. I. Fleming and S. K. Ghosh, Total Syntheses of (+)- and (-)-Nonactate Esters Using Silicon Compounds to Control the Stereochemistry, J. Chem. Soc., Chem. Commun., 1994, 2285-2286. (Full paper: 208)
  178. I. Fleming and S. K. Ghosh, A Total Synthesis of Nonactin, J. Chem. Soc., Chem. Commun., 1994, 2287-2288. (Full paper: 208)
  179. F. J. Blanco, P. Cuadrado, A. M. González, F. J. Pulido and I. Fleming, New Findings on the Regiochemistry of the Silylcupration of Allene, Tetrahedron Lett., 1994, 35, 8881-8882.
  180. I. Fleming and N. D. Kindon, Diastereoselectivity in the Preparation of β-Silyl Esters from αβ-Unsaturated Esters and Amides Attached to Chiral Auxiliaries, J. Chem. Soc. Perkin Trans. 1, 1995, 303-315.
  181. I. Fleming, R. Henning, D. C. Parker, H. E. Plaut and P. E. J. Sanderson, The Phenyldimethylsilyl Group as a Masked Hydroxy Group, J. Chem. Soc. Perkin Trans. 1, 1995, 317-337.
  182. I. Fleming and S. B. D. Winter, Controlling the Stereochemistry at C-15 in Prostaglandin Synthesis Using a Stereoconvergent Allylsilane Synthesis and a Silyl-to-Hydroxy Conversion, Tetrahedron Lett., 1995, 36, 1733-1734. (Full paper: 204)
  183. A. Barbero, P. Cuadrado, I. Fleming, A. M. González, F. J. Pulido and A. Sánchez, Synthesis of vinylsilanes by silyl-cupration of acetylenes using tert-butyldiphenylsilyl-cuprate reagents, J. Chem. Soc. Perkin Trans. 1, 1995, 1525-1532.
  184. I. Fleming, G. R. Jones, N. D. Kindon, Y. Landais, C. P. Leslie, I. T. Morgan, S. Peukert and A. K. Sarkar, Diastereoselectivity in the SE2" reaction of chiral pentadienylsilanes: a test for the relative importance of steric and electronic effects, J. Chem. Soc. Perkin Trans. 1, 1996, 1171-1196.
  185. I. Fleming and C. P. Leslie, Stereocontrol of Stereogenic Centres para on a Benzene Ring Using the SE2" Reaction of a Pentadienylsilane, J. Chem. Soc. Perkin Trans. 1, 1996, 1197-1203.
  186. I. Fleming, M. Solay and F. Stolwijk, The Reactions of Phenyldimethylsilyllithium with Nitriles, J. Organomet. Chem., 1996, 521, 121-124.
  187. I. Fleming and D. Lee, Conjugate Addition of Silyl Groups to β-Unsubstituted Enones, and Si-to-OH Conversion: a Synthesis of (±)-Lavandulol, Tetrahedron Lett., 1996, 37, 6929-6930. (Full paper: 205)
  188. I. Fleming, R. S. Roberts and S. C. Smith, The Phenyldimethylsilyllithium Reagent, Tetrahedron Lett., 1996, 38, 9395-9396. (Full paper: 195)
  189. A. Chénedé, N. Abd.Rahman and I. Fleming, Dehydration of α-Silylalcohols in the Reductive Conversion of Esters and Ketones into Alkenes, Tetrahedron Lett., 1997, 38, 2381-2382.
  190. A. Barbero, D. C. Blakemore, I. Fleming and R. N. Wesley, In search of open-chain 1,3-stereocontrol, J. Chem. Soc. Perkin Trans. 1, 1997, 1329-1352.
  191. S. Saito, K. Shimada, H. Yamamoto, E. Martínez de Marigorta and I. Fleming, A new synthetic route to allylsilanes: the reaction of silyllithium reagents with aromatic carbonyl compounds and aluminium tris(2,6-diphenylphenoxide)(ATPH), Chem. Commun., 1997, 1299-1300.
  192. I. Fleming, U. Ghosh, S. R. Mack and B. P. Clark, The reductive coupling of tertiary amides to give enediamines using PhMe2SiLi, Chem. Commun., 1998, 711-712. (Full paper: 234)
  193. I. Fleming, S. R. Mack and B. P. Clark, α-Aminocarbene or carbenoid formation in the reaction of a tertiary amide with PhMe2SiLi and its insertion into the Si-Li bond of a second equivalent, Chem. Commun., 1998, 713-714. (Full paper: 234)
  194. I. Fleming, S. R. Mack and B. P. Clark, Formation of α-dialkylamino alkyllithium intermediates in the reaction of N,N-dialkylamides with PhMe2SiLi followed by a second lithium reagent, and their alkylation, fragmentation, cyclisation and rearrangement by proton transfer, Chem. Commun., 1998, 715-716. (Full paper: 234)
  195. I. Fleming, R. S. Roberts and S. C. Smith, The preparation and analysis of the phenyldimethylsilyllithium reagent and its reaction with silyl enol ethers, J. Chem. Soc. Perkin Trans. 1, 1998, 1209-1214.
  196. I. Fleming, R. S. Roberts and S. C. Smith, The reduction of α-silyloxy ketones using phenyldimethylsilyllithium, J. Chem. Soc. Perkin Trans. 1, 1998, 1215-1228.
  197. I. Fleming, J. Frackenpohl and H. Ila, Cleavage of sulfonamides with phenyldimethylsilyllithium, J. Chem. Soc. Perkin Trans. 1, 1998, 1229-1235.
  198. I. Fleming and J. M. Mwaniki, A synthesis of enantiomerically enriched propargyl silanes, J. Chem. Soc. Perkin Trans. 1, 1998, 1237-1247.
  199. I. Fleming and N. K. Terrett, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of (±)-dihydronepetalactone using the SE2' reaction of an allylsilane, J. Chem. Soc. Perkin Trans. 1, 1998, 2645-2649.
  200. H.-F. Chow and I. Fleming, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of the (±)-Prelog-Djerassi lactone, J. Chem. Soc. Perkin Trans. 1, 1998, 2651-2662.
  201. I. Fleming and J. D. Kilburn, Stereocontrol in organic synthesis using silicon-containing compounds. A formal synthesis of (±)-thienamycin, J. Chem. Soc. Perkin Trans. 1, 1998, 2663-2671.
  202. I. Fleming and D. Higgins, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of a (±)-carbacyclin analogue with the geometry of the exocyclic double bond controlled by the protodesilylation of an allylsilane, J. Chem. Soc. Perkin Trans. 1, 1998, 2673-2678.
  203. I. Fleming and N. J. Lawrence, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of (-)-tetrahydrolipstatin using the alkylation of a β-silyl ester and the hydroboration of an allylsilane, J. Chem. Soc. Perkin Trans. 1, 1998, 2679-2686.
  204. I. Fleming and S. B. D. Winter, Stereocontrol in organic synthesis using silicon-containing compounds. A formal synthesis of prostaglandins controlling the stereochemistry at C-15 using a silyl-to-hydroxy conversion following a stereochemically convergent synthesis of an allylsilane, J. Chem. Soc. Perkin Trans. 1, 1998, 2687-2700.
  205. I. Fleming and D. Lee, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of (±)-lavandulol using a silyl-to-hydroxy conversion in the presence of 1,1-disubstituted and trisubstituted double bonds, J. Chem. Soc. Perkin Trans. 1, 1998, 2701-2709.
  206. I. Fleming and S. K. Ghosh, Stereocontrol in organic synthesis using silicon-containing compounds. Syntheses of (±)-2-deoxyribonalactone and (±)-arabonalactone, J. Chem. Soc. Perkin Trans. 1, 1998, 2711-2720.
  207. M. Ahmar, C. Duyck and I. Fleming, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of methyl (+)-nonactate, J. Chem. Soc. Perkin Trans. 1, 1998, 2721-2732.
  208. I. Fleming and S. K. Ghosh, Stereocontrol in organic synthesis using silicon-containing compounds. A synthesis of nonactin, J. Chem. Soc. Perkin Trans. 1, 1998, 2733-2747.
  209. I. Fleming, I. T. Morgan and A. K. Sarkar, The stereochemistry of the vinylogous Peterson elimination, J. Chem. Soc. Perkin Trans. 1, 1998, 2749-2763.
  210. I. Fleming and E. Martínez de Marigorta, Silyl-cupration of an acetylene followed by ring-formation, J. Chem. Soc. Perkin Trans. 1, 1999, 889-900.
  211. I. Fleming and A. K. Mandal, Unusual cyclopropanol formation from a β-silyl aldehyde, Chem. Commun., 1999, 923-924. (Full paper: 231)
  212. I. Fleming and C. Ramarao, Decarboxylative elimination of enol triflates as a general synthesis of acetylenes, Chem. Commun., 1999, 1113-1114. (Full paper: 232)
  213. I. Fleming and C. Ramarao, An approach to open-chain 1,5-stereocontrol using a silyl group, Chem. Commun., 2000, 2185-2186. (Full paper: 226)
  214. I. Fleming and A. K. Mandal, Trapping the tetrahedral intermediate in the 1,3-shift of an acetyl group using a triisopropylsilyl group, J. Indian Chem.Soc., 2000, 77, 593-598.
  215. I. Fleming, D. Hrovat and W. T. Borden, The origin of Felkin-Anh control from an electropositive substituent adjacent to the carbonyl group, J. Chem. Soc. Perkin Trans. 2, 2001, 331-338.
  216. M. A. Cubillo de Dios, I. Fleming, W. Friedhoff and P. D. W. Woode, Silyl-cupration of a propargylsilane as a test for the reversibility of a metallo-metallation, J. Organomet. Chem., 2001, 624, 69-72.
  217. D. J. Barden and I. Fleming, A by-product using TIPS protection - a warning, Chem. Commun., 2001, 2366-2367.
  218. M Buswell and I. Fleming, A synthesis of the enethiols of thioacylsilanes by the reaction of phenyldimethylsilyllithium with N,N-dimethylthioamides, ARKIVOC, 2002, 2002(vii), 46-51.
  219. I. Fleming and K. L. C. Pang, Determination of the extent to which an SE2' reaction of a propargylsilane is anti, Tetrahedron Lett., 2002, 43, 5985-5988. (Full paper: 229)
  220. I. Fleming, A. J. Lawrence, R. D. Richardson, D. S. Surry and M. C. West, 1,1-Disilylalcohols as d1 Synthons - Harnessing the 1,2-Brook Rearrangement, Helv. Chim. Acta, 2002, 85, 3349-3365.
  221. I. Fleming and M. G. Russell, Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides, Chem. Commun., 2003, 198-199. (Full paper: 234)
  222. I. Fleming, E. Marangon, C. Roni, M. G. Russell and S. Taliansky Chamudis, Reactions of phenyldimethylsilyllithium with β-N,N-dimethylaminoenones, Chem. Commun., 2003, 200-201. (Full paper: 230)
  223. M. Buswell and I. Fleming, The reaction of phenyldimethylsilyllithium with N-phenylpyrrolidone, Chem. Commun., 2003, 202-203. (Full paper: 234)
  224. J. E. Davies, I. Fleming and J. M. Goodman, A tricycloheptane product in cationic rearrangements, Org. Biomol. Chem., 2003, 1, 3570-3571.
  225. A. Chénedé, I. Fleming, R. Salmon and M. C. West, Cationic rearrangements controlled by the presence of a silyl group, J. Organomet. Chem., 2003, 686, 84-93.
  226. I. Fleming, P. Maiti and C. Ramarao, Stereocontrol of 1,5-related stereocentres using an intermediate silyl group - the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group, Org. Biomol. Chem., 2003, 1, 3989-4004.
  227. M. S. Betson and I. Fleming, The Ireland-Claisen rearrangement as a probe for the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group, Org. Biomol. Chem., 2003, 1, 4005-4016.
  228. M. S. Betson, I. Fleming and J. V. A. Ouzman, Diastereocontrol in open-chain nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group, Org. Biomol. Chem., 2004, 1, 4017-4024.
  229. M. J. C. Buckle, I. Fleming, S. Gil and K. L. C. Pang, Accurate determinations of the extent to which the SE2' reactions of allyl-, allenyl- and propargylsilanes are stereospecifically anti, Org. Biomol. Chem., 2004, 2, 749-769.
  230. I. Fleming, E. Marangon, C. Roni, M. G. Russell and S. Taliansky Chamudis, Reactions of phenyldimethylsilyllithium with β-N,N-dimethylaminoenones: A convenient synthesis of β-dimethyl(phenyl)silylacrylic acid and its derivatives, Can. J. Chem., 2004, 82, 325-332.
  231. S. C. Archibald, D. J. Barden, J. F. Y. Bazin, I. Fleming, C. F. Foster, A. K. Mandal, A. K. Mandal, D. Parker, K. Takaki, A. C. Ware, A. R. B. Williams and A. B. Zwicky, Stereocontrol in organic synthesis using silicon-containing compounds. Studies directed towards the synthesis of ebelactone A, Org. Biomol. Chem., 2004, 2, 1051-1064.
  232. I. Fleming and C. Ramarao, Decarboxylative elimination of enol triflates as a general synthesis of acetylenes, Org. Biomol. Chem., 2004, 2, 1504-1510.
  233. T. Buttler and I. Fleming, A synthesis of (±)-sparteine, Chem. Commun., 2004, 2404-2405. (Full paper: 235)
  234. M. Buswell, I. Fleming, U. Ghosh, S. Mack, M. G. Russell and B. P. Clark, The extraordinary reactions of phenyldimethylsilyllithium with N,N-disubstituted amides, Org. Biomol. Chem., 2004, 3, 3006-3017.
  235. T. Buttler, I. Fleming, S. Gonsior, B.-H. Kim, A.-Y. Sung and H.-G. Woo, A synthesis of (±)-sparteine, Org. Biomol. Chem., 2005, 3, 1557-1567.
  236. J. O. Daiss, C. Burschka, J. S. Mills, J. G. Montana, G. A. Showell, I. Fleming, C. Gaudon, D. Ivanovna, H. Gronemeyer and R. Tacke, Synthesis, Crystal Structure Analysis, and Pharmacological Characterization of Disila-bexarotene, A Disila-Analoge of the RXR-Selective Retinoid Agonist Bexarotene, Organometallics, 2005, 24, 3192-3199.
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